technologies : EHC®


EHC® Granules

Client Testimonial: Oregon Site

"Our client needed an in situ remedy that could selectively remove TCE from groundwater in the presence of hydrocarbon DNAPL. Bench trials demonstrated that EHC outperformed other technologies (emulsified oil and lactate-based). The subsequent pilot tests included creating a bioaugmented EHC permeable reactive barrier at depths ranging from 50 to 130 feet below ground, using traditional direct-push equipment. Five months following injection, the concentrations of TCE were reduced from approximately 100,000 ppb to below method reporting limits with sustained, negative redox conditions, and no accumulation of catabolites. Because of the relative cost, ease of implementation, and safety of the product, we expect to recommend future installations of EHC at this and many other sites."

-James Peale, Senior Hydrogeologist Maul Foster & Alongi, Inc.

EHC® Environmental Remediation Products

EHC® technology describes a family of remediation products used for the in situ treatment of groundwater and saturated soil impacted by heavy metals and persistent organic compounds such as chlorinated solvents, pesticides and energetics. The technology is a modification of our DARAMEND® technology which has been used since 1992 to treat over 3,600,000 tons of similarly effected soil and sediment. Both EHC® and DARAMEND® are the subjects of numerous patents owned by Adventus Intellectual Properties, Inc. (Adventus).

EHC® is a controlled-release, integrated carbon and zero valent iron (ZVI) source that yields redox potential (Eh) in the -500 to -650 mV range. This Eh is significantly lower than that achieved when using either organic materials (lactate, molasses, and sugars) or reduced metal alone. Eh potentials in this range facilitate the timely and effective removal of normally recalcitrant chlorinated organics (e.g., CT, PCE) and other persistent compounds (e.g., perchlorate) without the formation of potentially problematic intermediates, such as DCE/VC from the anaerobic degradation of PCE/TCE or CF/DCM from the anaerobic degradation of CT.

Watch this video to see the simulated effects of EHC injected as a PRB; plume cut-off of Carbon Tetrachloride. Site: Grain Silo Facility, Kansas USA.

EHC® Formulations

EHC® comes in a variety of formulations to meet the requirements unique to each site. Standard EHC® is a solid material available in pellets, granules or powders. EHC® can be applied via a variety of construction methods providing in situ source area treatment or plume management (Permeable Reactive Barriers).

  • EHC-M® is specially prepared for treatment of heavy metals.
  • EHC-O® contains a slow-release oxygen source for rapid removal of petroleum hydrocarbons and other compounds that are amenable to aerobic biodegradation processes.
  • EHC-A® is a liquid formulation provided as a suspendable solid or an aqueous solution for easy application to existing wells or other networks.

The organic component of EHC (fibrous organic material) is nutrient-rich, hydrophilic, and has high surface area; thus, it is an ideal support for growth of bacteria in the groundwater environment. As they grow on EHC particle surfaces, indigenous heterotrophic bacteria consume dissolved oxygen, thereby reducing the redox potential in groundwater. In addition, as the bacteria grow on the organic particles, they ferment carbon and release a variety of volatile fatty acids (VFAs, for example acetic, propionic, butyric), which diffuse from the site of fermentation into the groundwater plume and serve as electron donors for other bacteria, including dehalogenators and halorespiring species. Finally, the soluble ferrous sulfate particles provide substantial reactive surface area that stimulates direct chemical dechlorination and an additional drop in the redox potential of the groundwater via chemical oxygen scavenging. These physical, chemical, and biological processes combine to create an extremely reduced environment that stimulates chemical and microbiological dechlorination of otherwise persistent compounds

1. Comparison of Commercially Available In Situ Groundwater Treatment Products

PRODUCT
CARBON
ZVI
NUTRIENTS
BUFFERING
LONGEVITY (MONTHS)
COST
(US$/lb)
ISCR     EHC
Yes
Yes
Yes
Yes
12 - >60
$2.0
Lactate- based hrc’s
Yes
No
No
No
6 - >12
$5.0 – 8.0
Iron
No
Yes
No
No
80 – 120+
$0.2 – 0.5
Molasses
Yes
No
Yes
No
1 - 2
$0.2 – 1.0
Vegetable Oil
Yes
No
No
No
12 - >60
$0.5 – 0.7
Chitin
Yes
No
Yes
No
6 - 24
$2.0 – 3.0

 

Remediation products Soil Remediation Groundwater Remediation